Отримання молібдат-вмістного NI-TI подвійно-шарового гідроксиду одно стадійним зворотнім синтезом і вивчення його характеристик

Vitalii Solovov, Nikolai Nikolenko, Vadym Kovalenko, Valerii Kotok

Анотація


Зразок молібдат-вмістного Ni-Ti подвійно-шарового гідроксиду (ПШГ) був отриманий одно стадійним зворотнім синтезом: поступовим введенням розчину солей нікелю та титану в розчин лугу з додаванням гептамолібдату амонію при постійному перемішуванні та кімнатній температурі. Структура зразка як подвійно-шарового гідроксиду підтверджена результатами ІЧ-спектроскопії, РФА і деріватографії. За результатами ІЧ-спектроскопії було показано наявність в між шаровому просторі ПШГ гексамолібдат-аніонів. РСМА встановлено наступне співвідношення металів в синтезованому ПШГ Ni:Ti:Мо=1:0,19:0,22.

Ключові слова


молибдат-содержащий Ni-Ti слоистый двойной гидроксид; гептаамолибдат; одностадийный обратный синтез

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Посилання


Cavani F., Trifirò F., Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and applications. Catalysis today, 1991, 2(11), 173–301, doi: 10.1016/0920-5861(91)80068-K.

Shu X. et al. Formation of Ni-Ti-layered double hydroxides using homogeneous precipitation method. Solid State Sciences, 2006, 8, 634-639, doi: 10.1016/j.solidstatesciences.2006.02.029.

Zhang, W. H., Guo, X. D., He, J., Qian, Z. Y. Preparation of Ni(II)/Ti(IV) layered double hydroxide at high supersaturation. Journal of the European Ceramic Societyб 2008, 8(28), 1623–1629, doi: 10.1016/j.jeurceramsoc.2007.11.016.

Saber, O. Preparation and characterization of a new nano layered material, Co–Zr LDH. Journal of Materials Science, 2007, 23 (42), 9905–9912, doi: 10.1007/s10853-007-2097-5

Saber, O., Tagaya, H. Preparation of new layered double hydroxide, Co-V LDH. Rev. Adv. Mater. Sci., 2005, 10, 59–63, doi: 10.1007/s10847-004-4819-5.

Fan, G., Li, F., Evans, D. G., Duan, X. Catalytic applications of layered double hydroxides: recent advances and perspectives. Chem. Soc. Rev., 2014, 20(43), 7040–7066, doi: 10.1039/C4CS00160E.

Sels, B. F., De Vos, D. E., Grobet, P. J. et al. Molybdate- and tungstate-exchanged layered double hydroxides as catalysts for 1O 2 formation: characterization of reactive oxygen species and a critical evaluation of 1 O2 detection methods. The Journal of Physical Chemistry B., 1999, 50(103), 11114–11123, doi: 10.1021/jp992236z.

Cheng, J., Wang, X., Ma, C., Hao, Z. Novel Co-Mg-Al-Ti-O catalyst derived from hydrotalcite-like compound for NO storage/decomposition. Journal of Environmental Sciences, 2012, 3(24), 488–493, doi: 10.1016/S1001-0742(11)60796-1

Gao, Z. Y., Zhang, H. Photodegradation of Pentachlorophenol using NiO-coupled NiTiO3 Nanocomposites from Layered Precursor as Photocatalysts. Advanced Materials Research, 2011, 396–398, 411–416, doi: 10.4028/www.scientific.net/AMR.396-398.411.

Nikolenko, N. V., Kalashnykova, A. N., Solovov, V. A. et al. Peroxide-based route for the synthesis of zinc titanate powder. Arabian Journal of Chemistry, 2016, doi: 10.1016/j.arabjc.2016.06.018.

Mitchell, P. C. H., Wass, S. A. Propane dehydrogenation over molybdenum hydrotalcite catalysts. Applied Catalysis A: General, 2002, 1(225), 153–165, doi: 10.1016/S0926-860X(01)00862-6.

Klemkaitė-Ramanauskė, K., Žilinskas, A., Taraškevičius, R. et al. Preparation of Mg/Al layered double hydroxide (LDH) with structurally embedded molybdate ions and application as a catalyst for the synthesis of 2-adamantylidene(phenyl)amine Schiff base. Polyhedron, 2014, 68, 340–345, doi: 10.1016/j.poly.2013.11.009.

Taube, F. Characterization of aqueous peroxomolybdates with catalytic applicability. Thesis. Dept. of Chemistry, Umeå University, 2002, 65 p.

Vitalii Solovov, Nikolai Nikolenko, Vadym Kovalenko, Valerii Kotok Comparison of characteristics of Ni(II)-Ti(IV) layered double hydroxides synthesized by different coprecipitation techniques. IFSES 2016 Memory. International Forum for Science and Engineering Students, Guadalajara, Mexico, April, 2016, doi: 10.13140/RG.2.226569.95842.

Gao, Z. et al. Adsorption of Pentachlorophenol from Aqueous Solution on Dodecylbenzenesulfonate Modified Nickel Titanium Layered Double Hydroxide Nanocomposites. Ind. Eng. Chem. Res., 2011, 50, 5334 – 5345. doi: 10.1021/ie101766e.

Davantès, A., Lefèvre, G. In situ real time infrared spectroscopy of sorption of (poly)molybdate ions into layered double hydroxides. The Journal of Physical Chemistry A., 2013, 48(117), 12922–12929, doi: 10.1021/jp408885k.


Пристатейна бібліографія ГОСТ


1. Cavani, F. Hydrotalcite-type anionic clays: preparation, properties and applications. / F. Cavani, F. Trifirò, A. Vaccari // Catalysis today. – 1991. – Vol. 11, No. 2. –
P. 173–301. – doi: 10.1016/0920-5861(91)80068-K.
2. Shu, X. Formation of Ni-Ti-layered double hydroxides using homogeneous precipitation method / X. Shu [et al.] // Solid State Sciences. – 2006. – Vol. 8. – P. 634-639. – doi: 10.1016/j.solidstatesciences.2006.02.029.
3. Zhang, W. H. Preparation of Ni(II)/Ti(IV) layered double hydroxide at high supersaturation / W. H. Zhang, X. D. Guo, J. He, Z. Y. Qian // Journal of the European Ceramic Society. – 2008. – Vol. 28, No. 8. – P. 1623–1629. – doi: 10.1016/j.jeurceramsoc.2007.11.016.
4. Saber, O. Preparation and characterization of a new nano layered material, Co–ZrLDH / O. Saber // Journal of Materials Science. – 2007. – Vol. 42, No. 23. – P. 9905–9912. – doi: 10.1007/s10853-007-2097-5.
5. Saber, O. Preparation of new layered double hydroxide, Co-V LDH / O. Saber, H. Tagaya // Rev. Adv. Mater. Sci. – 2005. – Vol. 10. – P. 59–63. – doi: 10.1007/s10847-004-4819-5.
6. Fan, G. Catalytic applications of layered double hydroxides: recent advances and perspectives / G. Fan, F. Li, D. G. Evans, X. Duan // Chem. Soc. Rev. – 2014. –
Vol. 43, No. 20. – P. 7040–7066. – doi: 10.1039/C4CS00160E.
7. Sels, B. F. Molybdate- and tungstate-exchanged layered double hydroxides as catalysts for 1O 2 formation: characterization of reactive oxygen species and a critical evaluation of 1 O2 detection methods / B. F. Sels, D. E. De Vos, P. J. Grobet [et al.] // The Journal of Physical Chemistry B. – 1999. – Vol. 103, No. 50. – P. 11114–11123. – doi: 10.1021/jp992236z.
8. Cheng, J. Novel Co-Mg-Al-Ti-O catalyst derived from hydrotalcite-like compound for NO storage/decomposition / J. Cheng, X. Wang, C. Ma, Z. Hao // Journal of Environmental Sciences. – 2012. – Vol. 24, No. 3. –
P. 488–493. – doi: 10.1016/S1001-0742(11)60796-1.
9. Gao, Z. Y. Photodegradation of Pentachlorophenol using NiO-coupled NiTiO3 Nanocomposites from Layered Precursor as Photocatalysts / Z. Y. Gao, H. Zhang // Advanced Materials Research. – 2011. – Vol. 396–398. –
P. 411–416. – doi: 10.4028/www.scientific.net/AMR.396-398.411.
10. Nikolenko, N. V. Peroxide-based route for the synthesis of zinc titanate powder / N. V. Nikolenko, A. N. Kalashnykova, V. A. Solovov [et al.] // Arabian Journal of Chemistry. – 2016. – doi: 10.1016/j.arabjc.2016.06.018.
11. Mitchell, P. C. H. Propane dehydrogenation over molybdenum hydrotalcite catalysts / P. C. H. Mitchell, S. A. Wass // Applied Catalysis A: General. – 2002. –
Vol. 225, No. 1. – P. 153–165. – doi: 10.1016/S0926-860X(01)00862-6.
12. Klemkaitė-Ramanauskė, K. Preparation of Mg/Al layered double hydroxide (LDH) with structurally embedded molybdate ions and application as a catalyst for the synthesis of 2-adamantylidene(phenyl)amine Schiff base / K. Klemkaitė-Ramanauskė, A. Žilinskas, R. Taraškevičius [et al.] // Polyhedron. – 2014. – Vol. 68. –
P. 340–345. – doi: 10.1016/j.poly.2013.11.009.
13. Taube, F. Characterization of aqueous peroxomolybdates with catalytic applicability: Thesis / F. Taube. – Umeå : Dept. of Chemistry, Umeå University – 2002. – 65 p.
14. Solovov Vitalii Comparison of characteristics of Ni(II)-Ti(IV) layered double hydroxides synthesized by different coprecipitation techniques / Vitalii Solovov, Nikolai Nikolenko, Vadym Kovalenko, Valerii Kotok // IFSES 2016 Memory. – International Forum for Science and Engineering Students, Guadalajara, Mexico – April, 2016. – doi: 10.13140/RG.2.226569.95842.
15. Gao, Z. et al. Adsorption of Pentachlorophenol from Aqueous Solution on Dodecylbenzenesulfonate Modified Nickel Titanium Layered Double Hydroxide Nanocomposites / Z. Gao et al. // Ind. Eng. Chem. Res. – 2011. – Vol. 50. – P. 5334 – 5345. – doi: 10.1021/ie101766e
16. Davantès, A. In situ real time infrared spectroscopy of sorption of (poly)molybdate ions into layered double hydroxides / A. Davantès, G. Lefèvre // The Journal of Physical Chemistry A. – 2013. – Vol. 117, No. 48. – P. 12922–12929. – doi: 10.1021/jp408885k.




DOI: https://doi.org/10.20998/2413-4295.2016.42.34

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